Earlier this month, the Pet Shop Boys stopped by “The Graham Norton Show” in support of their just-released new best-of set, Ultimate. In the clip above, the duo performs its 1987 No. 1 hit “It’s a Sin” — one of the 19 tracks on that disc — on the BBC show before joining Norton and his other guests (Joan Rivers, Johnny Knoxville and Catherine Tate) for a chat.

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